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Supermax has about 700 customers across the globe including firms in the medical, automotive and food industries.
Supermax, based in Peterborough, said it was approached for the disposable gloves last week by the Department of Health and Social Care.
Managing director Iain Crawford said providing all its stock for NHS use was "the right and proper thing to do".
The Department of Health has been approached for comment.
Supermax has about 700 customers across the globe including firms in the medic